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Natural products appear to exert modulatory effects on this system, either by activating protective autophagy to clear damaged organelles and reduce oxidative load, or by inhibiting excessive autophagy to prevent unnecessary cellular degradation

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Examination of the GCL from these different organisms suggests that the interplay between the redox-sensitive thiol-switch and dimerization of the plant enzymes occurred later in evolution and may be related to compartmentalization of glutathione synthesis in the chloroplast (Gromes et al., 2008)